论文标题

低温下玻璃的通用“异常”特性真的是通用的吗?

Are universal "anomalous" properties of glasses at low temperatures truly universal?

论文作者

Ramos, Miguel A.

论文摘要

在低温下,玻璃的特定热CP和其他玻璃(从无定形固体到无序晶体)的特性与完全有序的晶体截然不同。几十年来,对眼镜的这种定性,甚至定量的普遍行为进行了彻底研究。但是,仍然缺乏对其起源和微观性质的清晰理解,不用说是一个封闭的理论。为了阐明此问题,我回顾了这项工作中的情况,主要是通过编译和讨论测量的许多眼镜和无序晶体的低温CP数据,并突出了“普遍性规则”的一些​​例外。因此,可以看到,与玻璃的其他低温特性相比,低温下“玻璃” CP过量的大小远非通用。更糟糕的是,某些没有明显疾病迹象的分子晶体在CP中表现出线性系数,大于许多无定形固体中的晶体,而后者的几个显示值可忽略不计。

The specific heat Cp and other properties of glasses (ranging from amorphous solids to disordered crystals) at low temperatures, are well known to be markedly different from those in fully-ordered crystals. For decades, this qualitative, and even quantitative, universal behavior of glasses has been thoroughly studied. However, a clear understanding of its origin and microscopic nature, needless to say a closed theory, is still lacking. To shed light on this matter, I review the situation in this work, mainly by compiling and discussing measured low-temperature Cp data of many glasses and disordered crystals, as well as highlighting a few exceptions to that "universality rule". Thus, one can see that, in contrast to other low-temperature properties of glasses, the magnitude of the "glassy" Cp excess at low temperature is far from being universal. Even worse, some molecular crystals without a clear sign of disorder exhibit linear coefficients in Cp larger than those found in many amorphous solids, whereas a few of the latter show negligible values.

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