论文标题

热力学的时间信息不确定性关系

Time-information uncertainty relations in thermodynamics

论文作者

Nicholson, Schuyler B., Garcia-Pintos, Luis Pedro, del Campo, Adolfo, Green, Jason R.

论文摘要

物理系统动力运动并创建固定时间的结构耗散能量并产生熵。无论是生活还是合成,执行这些动态功能的系统都必须平衡耗散和速度。在这里,我们表明能源和熵交换的速率受到速度限制 - 时间信息不确定性关系 - 由系统信息内容的变化率施加。这种不确定性关系界定了在变化热力学数量变化之前的时间与其初始标准偏差相同。从这个一般的结合中,我们建立了一个速度限制,用于热,工作,熵产生和熵流,具体取决于系统上的实验约束。在所有这些不等式中,瞬态动力学波动的时间尺度普遍受渔民信息的限制。此外,它们都有一种数学形式,可以反映量子力学中时间能量不确定性关系的mandelstam-tamm版本。这些在任意可观察速度的界限适用于远离热力学平衡的瞬态系统,与随机动力学或其功能的物理假设无关。

Physical systems that power motion and create structure in a fixed amount of time dissipate energy and produce entropy. Whether living or synthetic, systems performing these dynamic functions must balance dissipation and speed. Here, we show that rates of energy and entropy exchange are subject to a speed limit -- a time-information uncertainty relation -- imposed by the rates of change in the information content of the system. This uncertainty relation bounds the time that elapses before the change in a thermodynamic quantity has the same magnitude as its initial standard deviation. From this general bound, we establish a family of speed limits for heat, work, entropy production, and entropy flow depending on the experimental constraints on the system. In all of these inequalities, the time scale of transient dynamical fluctuations is universally bounded by the Fisher information. Moreover, they all have a mathematical form that mirrors the Mandelstam-Tamm version of the time-energy uncertainty relation in quantum mechanics. These bounds on the speed of arbitrary observables apply to transient systems away from thermodynamic equilibrium, independent of the physical assumptions about the stochastic dynamics or their function.

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