论文标题
添加性和常规制造的奥氏体不锈钢之间的氢化耐药性的比较研究
Comparative study of hydrogen embrittlement resistance between additively and conventionally manufactured austenitic stainless steels
论文作者
论文摘要
304L(18wt。%Cr,8-10wt。%Ni)在激光粉末 - 融合(LPBF)制造的奥氏体不锈钢(ASS)中,通过电化氢预先充电后进行了抗精油测试,并与两种不同的处理式(II)(II)(II)铸造(II)(II)铸造(II)(II)等级(II),并将其与常规的304L屁股进行比较(II),并与(II)相比(TMT)。结果表明,氢气的氢气导致CA样品的延展性显着降低,但是对于LPBF和CA-TMT样品,仅观察到氢的影响很小。发现与氢辅助的开裂行为与应变诱导的马塞塞他的转化密切相关。另外,在CA样品中,α马氏体的量高于其他样品,这表明严重的氢含量可以与奥氏体的机械稳定性低相关。详细的微观结构表征表明,CA样品的高奥斯丁岩稳定性主要归因于γ矩阵内部的保留含量和化学不均匀性(接近Delta接近Delta的Gamma具有〜2wt。%Cr的Cr,但降低了2wt。%ni ni),但TMT增强了化学性质和化学性质的稳定性。相比之下,LPBF工艺直接引导,即没有任何热机械处理,到达具有均匀元素分布的完全奥氏体结构。这些结果证实,γ矩阵内部的三角洲和化学不均匀性的存在,该基质促进了变形诱导的马氏体转化以及在伽马 - 阿尔法界面处的相关H富集,是严重H辅助失效的主要原因。
Hydrogen embrittlement in 304L (18wt.% Cr, 8-10wt.% Ni) austenitic stainless steel (ASS) fabricated by laser powder-bed-fusion (LPBF) was investigated by tensile testing after electrochemical hydrogen pre-charging and compared to conventionally available 304L ASSs with two different processing histories, (i) casting plus annealing (CA) and (ii) CA plus thermomechanical treatment (TMT). It was revealed that hydrogen-charging led to a significant reduction in ductility for the CA sample, but only a small effect of hydrogen was observed for the LPBF and CA-TMT samples. Hydrogen-assisted cracking behavior was found to be strongly linked to strain-induced martensitic transformation. In addition, the amount of alpha' martensite was much higher in the CA sample than in other samples, suggesting that severe hydrogen embrittlement can be correlated with the low mechanical stability of austenite. Detailed microstructural characterization showed that low austenite stability of the CA sample was mainly attributed to the retained content of delta ferrite and the chemical inhomogeneity inside the gamma matrix (gamma close to delta has ~2 wt.% higher Cr but ~2 wt.% lower Ni), but TMT enhanced the chemical homogeneity and thus austenite stability. By contrast, the LPBF process led directly, i.e. without any thermomechanical treatment, to a fully austenitic structure with homogeneous elemental distribution in the ASS. These results confirmed that the presence of delta and the chemical inhomogeneity inside gamma matrix, which promoted the deformation-induced martensitic transformation and the associated H enrichment at the gamma-alpha' interface, was the primary reason for the severe H-assisted failure.