论文标题

等离震泡中的气蒸气相互作用

Gas-Vapor Interplay in Plasmonic Bubble Shrinkage

论文作者

Zaytsev, Mikhail E., Wang, Yuliang, Zhang, Yuhang, Lajoinie, Guillaume, Zhang, Xuehua, Prosperetti, Andrea, Zandvliet, Harold J. W., Lohse, Detlef

论文摘要

对浸入液体并被谐振光源照射的金属纳米颗粒形成的等离子纳米颗粒形成的等离子气泡的收缩动力学的理解对于在众多应用中使用这些气泡至关重要。在本文中,我们在实验上表明并从理论上解释了其收缩过程中的等离子体气泡经历了两个不同的阶段:首先,由蒸气凝结控制的快速部分气泡收缩,其次是缓慢的扩散控制气泡溶解。气泡形成的历史在第一阶段的收缩动力学中起着重要作用,因为它决定了气泡组成中的气蒸气比。较高的激光功率会导致更多的蒸发气泡,而较长的脉冲和较高的溶解空气浓度会导致更多的气泡。第二阶段的动力学几乎不取决于气泡形成的历史,即激光功率和脉冲持续时间,但强烈在溶解的空气浓度上,这定义了气泡界面处的浓度梯度。最后,对于第二阶段的气泡溶解(随着空气浓度的降低),我们观察到从$ r(t)\ propto(t_0 -t) ^{1/3} $缩放定律到$ r(t)\ propto(t _0- t _0- t)

The understanding of the shrinkage dynamics of plasmonic bubbles formed around metallic nanoparticles immersed in liquid and irradiated by a resonant light source is crucial for the usage of these bubbles in numerous applications. In this paper we experimentally show and theoretically explain that a plasmonic bubble during its shrinkage undergoes two different phases: first, a rapid partial bubble shrinkage governed by vapor condensation and, second, a slow diffusion-controlled bubble dissolution. The history of the bubble formation plays an important role in the shrinkage dynamics during the first phase, as it determines the gas-vapor ratio in the bubble composition. Higher laser powers lead to more vaporous bubbles, while longer pulses and higher dissolved air concentrations lead to more gaseous bubbles. The dynamics of the second phase barely depends on the history of bubble formation, i.e. laser power and pulse duration, but strongly on the dissolved air concentration, which defines the concentration gradient at the bubble interface. Finally, for the bubble dissolution in the second phase, with decreasing dissolved air concentration, we observe a gradual transition from a $R(t) \propto (t_0 - t) ^{1/3}$ scaling law to a $R(t) \propto (t_0 - t) ^{1/2}$ scaling law, where $t_0$ is the lifetime of the bubble and theoretically explain this transition.

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