论文标题

等离子Au纳米颗粒的增强的光催化活性掺入MOS $ _2 $纳米片以降解有机染料

Enhanced photocatalytic activity of plasmonic Au nanoparticles incorporated MoS$_2$ nanosheets for degradation of organic dyes

论文作者

Rani, Anjali, Patel, Arun Singh, Chakraborti, Anirban, Singh, Kulvinder, Sharma, Prianka

论文摘要

在本文中,我们研究了等离子Au纳米颗粒(NP)装饰对MOS $ _2 $纳米片的光催化效率的影响。 Au NP通过化学还原方法在化学去角质MOS $ _2 $纳米片的表面生长。 Au-mos $ _2 $纳米结构(NSS)的特征是X射线衍射仪,拉曼光谱仪,吸收分光光度计和透射电子显微镜。去角质MOS $ _2 $和AU-MOS $ _2 $ NSS用于研究有机染料甲基红(MR)和甲基蓝(MB)的光催化降解。在紫外可见的光照射下,原始MOS $ _2 $显示了MR的照片降解效率在30%至46.9%的MR,MB的23.3%至44%之间,分别从30分钟到120分钟。但是,Au-mos $ _2 $ NSS具有最大AU NPS浓度的NSS显示,MR的降解效率从70.2升至96.7%,MB的降解效率从65.2%到94.3%。两种染料的降解效率的流形增强具有AU-MOS $ _2 $ NSS的染料可能归因于NSS中充当电荷捕获位点的Au NP的存在。我们认为,这项研究将在与环境降解的不良影响作斗争时可能有潜在的应用,这对人类和生物多样性构成了重大威胁。

In the present paper, we investigate the effect of plasmonic Au nanoparticles (NPs) decoration on the photocatalytic efficiency of MoS$_2$ nanosheets. The Au NPs are grown on the surface of chemically exfoliated MoS$_2$ nanosheets by chemical reduction method. Au-MoS$_2$ nanostructures (NSs) are characterized by X-ray diffractometer, Raman spectrometer, absorption spectrophotometer, and transmission electron microscopy. Exfoliated MoS$_2$ and Au-MoS$_2$ NSs are used to study the photocatalytic degradation of organic dyes methyl red (MR) and methylene blue (MB). Under UV-Visible light irradiation, pristine MoS$_2$ shows photo degradation efficiencies between 30% to 46.9% for MR and 23.3% to 44% for MB, with varying exposure times from 30 to 120 min, respectively. However, Au-MoS$_2$ NSs with maximum Au NPs concentration show enhanced degradation efficiency from 70.2 to 96.7% for MR, and from 65.2 to 94.3% for MB. The manifold enhancement of degradation efficiency for both the dyes with Au-MoS$_2$ NSs may be attributed to the presence of Au NPs acting as charge trapping sites in the NSs. We believe this study would have potential application in battling the ill-effects of environmental degradation, which poses a major threat to humans as well as biodiversity.

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