论文标题
在胶体系统中呈指数级冷却
Exponentially faster cooling in a colloidal system
论文作者
论文摘要
随着冷却物体的温度随着热量平衡的放松而降低,直观地假设,热物体应比温暖的物体更冷却。然而,大约2300年前,亚里士多德观察到“快速冷却热水,首先将其放入阳光下”。在1960年代,这种违反直觉现象被重新发现为“热水可以比冷水更快冻结”,并已被称为MPEMBA效应。此后,它成为了许多实验研究和一些争议的主题。尽管已经提出了许多特定的机制,但就根本原因而言尚无一般共识。在这里,我们在受控的环境中演示了mpemba效应 - 浸入水中的胶体系统的热淬灭,该胶体系统用作热水浴。我们的结果是可重现的,并与基于最近提出的理论框架的计算进行定量一致。通过仔细选择参数,我们观察到比最近预测的强MPEMBA效应一致的冷却速度比使用典型参数观察到的冷却速度要快。我们的实验概述了加速去除热量和放松至热平衡所需的通用条件,并支持了以下想法:MPEMBA效应不仅是关于水如何将水冷冻到冰中的科学好奇心,这是水的许多异常特征之一 - 而是针对广泛范围的广泛范围的原始型号的原型。
As the temperature of a cooling object decreases as it relaxes to thermal equilibrium, it is intuitively assumed that a hot object should take longer to cool than a warm one. Yet, some 2,300 years ago, Aristotle observed that "to cool hot water quickly, begin by putting it in the sun". In the 1960s, this counterintuitive phenomenon was rediscovered as the statement that "hot water can freeze faster than cold water" and has become known as the Mpemba effect; it has since been the subject of much experimental investigation and some controversy. Although many specific mechanisms have been proposed, no general consensus exists as to the underlying cause. Here we demonstrate the Mpemba effect in a controlled setting - the thermal quench of a colloidal system immersed in water, which serves as a heat bath. Our results are reproducible and agree quantitatively with calculations based on a recently proposed theoretical framework. By carefully choosing parameters, we observe cooling that is exponentially faster than that observed using typical parameters, in accord with the recently predicted strong Mpemba effect. Our experiments outline the generic conditions needed to accelerate heat removal and relaxation to thermal equilibrium and support the idea that the Mpemba effect is not simply a scientific curiosity concerning how water freezes into ice - one of the many anomalous features of water - but rather the prototype for a wide range of anomalous relaxation phenomena of broad technological importance.