论文标题
评估相变和放松过程中的记忆效应
Evaluation of memory effects at phase transitions and during relaxation processes
论文作者
论文摘要
我们建议用非平稳的广义langevin方程来描述相变的动力学。通过构造,该方程在时间上是非本地的,即〜它涉及记忆效应,其强度受内存内核的影响。通常,确定基于基础显微镜运动方程的物理起源和记忆效应的程度是一项艰巨的任务。因此,我们建议将记忆内核的程度与实验观察到的数量相关联,例如诱导时间和相变过程的持续时间。使用简单的运动学模型,我们表明,内存内核的程度与过渡持续时间和相同数量级的持续时间呈正相关,而诱导时间的分布没有效果。该观察结果是在几个模型系统的示例中测试的,我们为其运行了分子动力学模拟:修改后的Potts模型,偶极气,浴中的无谐弹簧和成核问题。所有这些情况都与简单的理论模型一致。
We propose to describe the dynamics of phase transitions in terms of a non-stationary Generalized Langevin Equation for the order parameter. By construction, this equation is non-local in time, i.e.~it involves memory effects whose intensity is governed by a memory kernel. In general, it is a hard task to determine the physical origin and the extent of the memory effects based on the underlying microscopic equations of motion. Therefore we propose to relate the extent of the memory kernel to quantities that are experimentally observed such as the induction time and the duration of the phase transformation process. Using a simple kinematic model, we show that the extent of the memory kernel is positively correlated with the duration of the transition and of the same order of magnitude, while the distribution of induction times does not have an effect. This observation is tested at the example of several model systems, for which we have run Molecular Dynamics simulations: a modified Potts-model, a dipole gas, an anharmonic spring in a bath and a nucleation problem. All these cases are shown to be consistent with the simple theoretical model.