论文标题
缺陷诱导聚合物聚集体:一项理论研究
Defects induced polymer aggregates: A theoretical study
论文作者
论文摘要
。我们考虑在存在缺陷的情况下,考虑到高斯聚合物链的三维模型,以了解由缺陷诱导聚集体的聚合物聚集体的形成。这些缺陷充当了单体的有吸引力的中心,并且会诱导链中链中的单体的聚集。已经使用分析计算表明,当缺陷在所有可能的三个维度上具有扩展时,聚合物聚集体的形成受到青睐。我们还计算了相关的其他热动力参数(即,单体的平均数量和链中链的平均大小)的聚合物聚集体以证明我们的发现是合理的。
. We consider three dimensional model of the Gaussian polymer chain in the presence of defects to understand the formation of a polymer aggregate where the aggregate is induced by the defects. The defects are acting as an attractive centres of the monomers and it induces aggregation of the monomers of the chain around the defects. It has been shown using the analytical calculations that the formation of a polymer aggregates are favoured when the defects have extensions in all the possible three dimensions. We have also calculated relevant other thermo-dynamical parameters (i. e. the average number of the monomers and the average size of the chain about the defect line) of the polymer aggregates to justify our findings.