论文标题

在单轴应力和磁场下,元磁赫斯勒ni-mn-In的多层次效应

Multicaloric effects in Metamagnetic Heusler Ni-Mn-In under uniaxial stress and magnetic field

论文作者

Gràcia-Condal, Adrià, Gottschall, Tino, Pfeuffer, Lukas, Gutfleisch, Oliver, Planes, Antoni, Mañosa, Lluís

论文摘要

一方面,世界对人造寒冷的渴望日益严重,另一方面越来越严格的气候目标对人类构成了巨大的挑战。基于固态制冷剂的新型,高效且对环保的制冷技术可以为传统蒸汽压缩机中使用的气候损害物质带来的问题提供一种方法。多核材料由于其温度较大而脱颖而出,因此可以通过应用不同的外部刺激(例如磁性,电场或机械场)引起。尽管应用的潜力很高,而且这组材料的有趣物理学,但只有很少的研究集中于他们通过直接方法进行的研究。在本文中,我们报告了所有相关物理量的高级表征,这些物理量决定了Ni-Mn-In-In-In Heusler化合物的多核作用。我们已经使用了专门设计的量热仪来确定磁场和单轴应力对这种元磁形状合金的组合作用而产生的等温熵和绝热温度变化。从这些结果中,我们可以得出结论,通过单轴应力和磁场的适当变化,这种合金的多层反应在很大程度上超过了合金的热量响应,仅受到单个刺激的影响。我们预计我们的发现可以应用于其他多材料材料,从而激发了基于多层次效应的制冷设备的开发。

The world's growing hunger for artificial cold on the one hand, and the ever more stringent climate targets on the other, pose an enormous challenge to mankind. Novel, efficient and environmentally friendly refrigeration technologies based on solid-state refrigerants can offer a way out of the problems arising from climate-damaging substances used in conventional vapor-compressors. Multicaloric materials stand out because of their large temperature changes which can be induced by the application of different external stimuli such as a magnetic, electric, or a mechanical field. Despite the high potential for applications and the interesting physics of this group of materials, only few studies focus on their investigation by direct methods. In this paper, we report on the advanced characterization of all relevant physical quantities that determine the multicaloric effect of a Ni-Mn-In Heusler compound. We have used a purpose-designed calorimeter to determine the isothermal entropy and adiabatic temperature changes resulting from the combined action of magnetic field and uniaxial stress on this metamagnetic shape-memory alloy. From these results, we can conclude that the multicaloric response of this alloy by appropriate changes of uniaxial stress and magnetic field largely outperforms the caloric response of the alloy when subjected to only a single stimulus. We anticipate that our findings can be applied to other multicaloric materials, thus inspiring the development of refrigeration devices based on the multicaloric effect.

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