论文标题

旋转重新定位和水晶场修改ho $ _ {1-y} $ gd $ _y $ al $ _2 $ compounds

Spin reorientations and crystal field modification in Ho$_{1-y}$Gd$_y$Al$_2$ compounds

论文作者

De Sousa, V. S. R., Silva, L. E. L., Gomes, A. M., von Ranke, P. J.

论文摘要

我们已经对旋转重新定位过渡进行了实验和理论研究,ho $ _ {1-y} $ gd $ _y $ al $ _2 $化合物。在HO $ _ {1-y} $ gd $ _y $ al $ _2 $系列($ y $ = 0、0.25、0.5、0.5、0.75和1.0)中,已经对五个选定样品进行了晶体学,磁和量热测量。从结果来看,观察到晶格参数的线性增加随GD-content的函数($ x $)的函数。磁化测量表明,所有样品都呈现共线性铁磁。进行了特定的热量测量,以详细介绍为Hoal $ _2 $左右出现的一阶自旋重新定向转变(FOSRT)。此外,我们研究了GD含量的增加如何影响这种相变的特征。我们的结果表明,自旋重新定向过渡温度略有修改,随着hoal $ _2 $的GD增加,温度降低,而对于选定的浓度最高为x = 0.75,则保持过渡的一阶特征。这种行为可能导致在宽的温度范围内产生较大的制冷剂能力(RC),这是评估此类化合物的磁电效应(MCE)的重要参数。通过包括晶体场,交换和Zeeman相互作用的模型汉密尔顿模型的理论分析揭示了随着GD含量增加而作用于HO ION的晶体场的修饰。

We have performed an experimental and theoretical investigation on the spin reorientation transitions Ho$_{1-y}$Gd$_y$Al$_2$ compounds. Crystallographic, magnetic and calorimetric measurements have been performed for five selected samples in the Ho$_{1-y}$Gd$_y$Al$_2$ series ($y$ = 0, 0.25, 0.5, 0.75 and 1.0). From the results, a linear increase in the lattice parameter as a function of Gd-content ($x$) is observed. Magnetization measurements show that all samples present collinear ferromagnetism. Specific heat measurements were performed in order to detail the first-order spin reorientation transition (FOSRT) that appears for HoAl$_2$ around 20 K. Furthermore, we investigated how the increase in Gd content affects the character of such phase transition. Our results show a slightly modification in the spin reorientation transition temperature, which moves to lower temperatures as Gd is increased in HoAl$_2$, whereas for the selected concentrations up to x = 0.75 the first-order character of the transition is maintained. Such behavior may lead to a large refrigerant capacity (RC) over a wide temperature range, which is an important parameter to evaluate the magnetocaloric effect (MCE) of such compounds. The theoretical analysis by means of a model Hamiltonian that includes crystal field, exchange and Zeeman interactions reveals a modification in the crystal-field acting on Ho ions as Gd-content is increased.

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