论文标题

增强高P/T燃料喷雾剂的预测能力;使用PC-SAFT的非理想热力学建模

Enhancing the predictive capabilities for high P/T fuel sprays; non-ideal thermodynamic modelling using PC-SAFT

论文作者

Koukouvinis, Phoevos, Vidal-Roncero, Alvaro, Rodriguez, Carlos, Gavaises, Manolis, Pickett, Lyle

论文摘要

目前的工作旨在调查发动机燃烧网络(ECN)喷雾剂的高压/高温燃料注入时发生的复杂现象。虽然在文献中通常使用传统的立方体方程模型来处理跨临界混合案例,但这种模型在准确预测液体密度和声音速度方面可能不足。本研究的目的是采用一般列表方法,该方法可应用于任何类型的热力学闭合。同时,采用基于扰动链统计的流体理论(PC-SAFT)的更先进的模型来创建热力学表,因为它被证明优于传统的立方模型,同时还具有预测蒸气 - 液体平衡的能力。该模型已用于十二烷和氮混合,对应于众所周知的喷雾条件。在实验误差中,发现了在温度和质量分数方面的蒸气渗透和混合。同样,热力学状态与绝热的同质混合曲线很好地对应,证明了该方法的能量保守性质。

The present work aims to investigate the complex phenomena occurring during high-pressure/high-temperature fuel injection of the Engine Combustion Network (ECN) Spray-A case. While commonly in the literature transcritical mixing cases are approached using traditional cubic equation-of-state models, such models can prove insufficient in the accurate prediction of liquid density and speed of sound. The purpose of the present investigation is to employ a general tabulated approach which can be applied to any type of thermodynamic closure. At the same time, a more advanced model based on the Perturbed-Chain Statistical Associating Fluid Theory (PC-SAFT) is employed to create the thermodynamic table, as it is proven superior to the traditional cubic models, while also having the capacity of predicting Vapor-Liquid-Equilibrium. The model has been used for a combination of dodecane and nitrogen mixing, corresponding to the well known Spray-A conditions. Vapor penetration and mixing both in terms of temperature and mass fraction are found in agreement to experiments, within the experimental errors. Also, the thermodynamic states correspond well with the adiabatic isobaric-mixing curve, demonstrating the energy-conservative nature of the approach.

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