论文标题

经济上可行的二氧化碳电气嵌入乙烷氧化物制造中

Economically viable CO2 electroreduction embedded within ethylene oxide manufacturing

论文作者

Barecka, Magda H., Ager, Joel W., Lapkin, Alexei A.

论文摘要

将CO2(CO2R)转化为燃料和化学物质的电化学转化都可以减少CO2排放量,并在可再生发电的显着扩展情况下进行清洁制造。但是,大规模的过程部署目前受到不利的过程经济学的限制,这是由于获得纯二氧化碳,反应产品的分离和增加后勤工作的巨大上流和下游成本而产生的。我们发现了一种在经济上可行的废物二氧化碳回收方法,以解决这些挑战。我们的方法基于将CO2R单元集成到现有的制造过程中:氧化乙烷(EO)生产,该生产将CO2作为副产品排放。标准的EO工艺将废物二氧化碳与气流分开,因此可以在EO工厂以无需额外的费用在EO植物上提供电源。二氧化碳可以转化为富含乙烯的流,并在现场回收回EO反应堆,EO反应堆使用乙烯作为原材料,并且可以同时将阳极产物(氧)与EO生产反应同时价值。如果由可再生电源提供动力,该过程将显着(约80%)减少EO制造工厂的CO2排放。灵敏度分析表明,回收方法在短期内可以在经济上可行,并且其回报时间在碳税较高和/或获得低成本电源的地区可能低至1 - 2年。

Electrochemical conversion of CO2 (CO2R) into fuels and chemicals can both reduce CO2 emissions and allow for clean manufacturing in the scenario of significant expansion of renewable power generation. However, large-scale process deployment is currently limited by unfavourable process economics resulting from significant up- and down-stream costs for obtaining pure CO2, separation of reaction products and increased logistical effort. We have discovered a method for economically viable recycling of waste CO2 that addresses these challenges. Our approach is based on integration of a CO2R unit into an existing manufacturing process: ethylene oxide (EO) production, which emits CO2 as a by-product. The standard EO process separates waste CO2 from gas stream, hence the substrate for electroreduction is available at an EO plant at no additional cost. CO2 can be converted into an ethylene-rich stream and recycled on-site back to the EO reactor, which uses ethylene as a raw material, and also the anode product (oxygen) can be simultaneously valorized for the EO production reaction. If powered by a renewable electricity source, the process will significantly (ca. 80%) reduce the CO2 emissions of an EO manufacturing plant. A sensitivity analysis shows that the recycling approach can be economically viable in the short term and that its payback time could be as low as 1-2 years in the regions with higher carbon taxes and/or with access to low-cost electricity sources.

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