论文标题

从半导体正常状态以$ 1T $ -TISE $ _ {2} $从半导体出现的激子绝缘子

Excitonic insulator emerging from semiconducting normal state in $1T$-TiSe$_{2}$

论文作者

Bok, Jin Mo, Hwang, Jungseek, Choi, Han-Yong

论文摘要

预计电子孔对的Bose-Einstein凝结物可能会出现一种新的物质,即激发型绝缘体(EI)状态。建议一些候选材料,但难以证实证实其存在。最近的作品为关键温度$ t_c \ t_c \ of $ 1t $ -tise $ _ {2} $的电荷密度波(CDW)状态的EI图片提供了新的支持。然而,与其建立的一个重要链接是表明,仅库仑互动确实遵循了所测量的$ t_c $的大部分,而$ t_c $的定量匹配可能需要电子衬托耦合的帮助。这将确定CDW主要是由库仑交互作用形成的,并有助于确认tise $ _2 $的EI视图。在这里,我们通过使用特定于材料的电子结构求解激子差距方程来提供此类计算。我们获得没有拟合参数的情况下,$ t_c \ t_c \ pm 27 $ k对于$ e_g \ \ 74 \ pm 15 $ mev的普通状态间隙。似乎来自库仑的$ t_c $的$ t_c $为最近确定的$ e_g $的实验$ t_c $的大部分。 $ T_C $的测量掺杂依赖性也令人满意地复制。同样与实验一致的是光发射光谱和状态密度的一组计算。上面的半导体状态和以下$ t_c $的EI在一起,应给出$ 1T $ -TISE $ _2 $的连贯图片。

A new state of matter, an excitonic insulator (EI) state, was predicted to emerge from Bose-Einstein condensation of electron-hole pairs. Some candidate materials were suggested but it has been elusive to confirm its existence. Recent works gave renewed support for the EI picture of the charge density wave (CDW) state below the critical temperature $T_c \approx 200 $ K of $1T$-TiSe$_{2}$. Yet, an important link to its establishment is to show that a majority fraction of the measured $T_c$ indeed follows from the Coulomb interaction alone, while a quantitative match of the $T_c$ may require assistance from the electron-lattice coupling. This will establish that the CDW is formed predominantly by the Coulomb interaction and help confirm the EI view for TiSe$_2$. Here, we provide such calculations by solving the exciton gap equation with material specific electronic structures. We obtain, with no fitting parameters, $T_c \approx 135 \pm 27$ K for the normal state gap of $E_g \approx 74 \pm 15$ meV. It seems that the calculated $T_c$ from Coulomb interaction gives a majority fraction of experimental $T_c$ for recently determined values of $E_g$. The measured doping dependence of $T_c$ was satisfactorily reproduced as well. Also in agreement with experiments are the same set of calculations of the photoemission spectroscopy and density of states. The semiconducting state above and EI below $T_c$ together should give a coherent picture of $1T$-TiSe$_2$.

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