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We analyze the best achievable performance of Bayesian learning under generative models by defining and upper-bounding the minimum excess risk (MER): the gap between the minimum expected loss attainable by learning from data and the minimum expected loss that could be achieved if the model realization were known. The definition of MER provides a principled way to define different notions of uncertainties in Bayesian learning, including the aleatoric uncertainty and the minimum epistemic uncertainty. Two methods for deriving upper bounds for the MER are presented. The first method, generally suitable for Bayesian learning with a parametric generative model, upper-bounds the MER by the conditional mutual information between the model parameters and the quantity being predicted given the observed data. It allows us to quantify the rate at which the MER decays to zero as more data becomes available. Under realizable models, this method also relates the MER to the richness of the generative function class, notably the VC dimension in binary classification. The second method, particularly suitable for Bayesian learning with a parametric predictive model, relates the MER to the minimum estimation error of the model parameters from data. It explicitly shows how the uncertainty in model parameter estimation translates to the MER and to the final prediction uncertainty. We also extend the definition and analysis of MER to the setting with multiple model families and the setting with nonparametric models. Along the discussions we draw some comparisons between the MER in Bayesian learning and the excess risk in frequentist learning.