论文标题
成像铁电体:电荷梯度显微镜(CGM)与潜在梯度显微镜(PGM)
Imaging Ferroelectrics: Charge Gradient Microscopy (CGM) versus Potential Gradient Microscopy (PGM)
论文作者
论文摘要
2014年,首先报道了电荷梯度显微镜(CGM)作为一种新的扫描探针成像模式,特别是适合铁电的表征。该技术的实施很简单;它涉及监测电流,这些电流自发地在被动导电的原子力显微镜尖端和地球之间发育,因为在样品表面扫描了尖端。但是,关于对比的基本起源以及与相关的铁电微观结构有关的含义的细节尚未完全了解。在此,通过比较来自CGM和Kelvin探针力显微镜(KPFM)的信息,从相同组合的铁电域(在Niobate和Titanate锂中)获得,我们表明CGM合理地反映了测得的表面电位的空间衍生物。这在概念上与测量表面边界电荷密度或任何相关筛选电荷中的局部梯度有所不同:毕竟,即使极化完全是平面内,我们也会看到清晰的CGM信号。因此,我们建议铁电中的CGM可以更准确地称为潜在梯度显微镜(PGM)。有趣的是,在所有检查的情况下,测得的表面电势(通过KPFM确定和通过整合CGM信号确定)的迹象与真空中完全清洁的铁电的直觉预期相反。这通常是由于在铁电表面上的电荷积累而被认为不容易去除的。
In 2014, Charge Gradient Microscopy (CGM) was first reported as a new scanning probe imaging mode, particularly well-suited for the characterisation of ferroelectrics. The implementation of the technique is straightforward; it involves monitoring currents that spontaneously develop between a passive conducting atomic force microscopy tip and Earth, as the tip is scanned across the specimen surface. However, details on the fundamental origin of contrast and what images mean, in terms of associated ferroelectric microstructures, are not yet fully understood. Here, by comparing information from CGM and Kelvin Probe Force Microscopy (KPFM), obtained from the same sets of ferroelectric domains (in both lithium niobate and barium titanate), we show that CGM reasonably reflects the spatial derivative of the measured surface potential. This is conceptually different from measuring local gradients in the surface bound-charge density or in any associated screening charges: after all, we see clear CGM signals, even when polarisation is entirely in-plane. We therefore suggest that CGM in ferroelectrics might be more accurately called Potential Gradient Microscopy (PGM). Intriguingly, in all cases examined, the measured surface potential (determined both through KPFM and by integrating the CGM signal) is of the opposite sign to that intuitively expected for a completely clean ferroelectric in vacuum. This is commonly observed and presumed due to a charge accumulation on the ferroelectric surface which is not easily removed.