论文标题
(a)对称Shuttleworth效果的软润湿
Soft wetting with (a)symmetric Shuttleworth effect
论文作者
论文摘要
与刚性基板上的润湿相比,软聚合物底物的润湿带来了多种复杂性。液体的接触角不再受杨定律的控制,而是受底物的散装和表面变形的影响。最重要的是,弹性接口表现出表面能,取决于它们的拉伸程度 - 一种称为Shuttleworth效应(或表面弹性)的特征。在这里,我们提出了两种模型,我们可以在存在强大的Shuttleworth效应的情况下探索滴落的润湿。第一个模型在特征上是宏观的,并且通过新霍克弹性始终如一地说明了较大的变形。第二个模型是基于润湿的介观描述,使用了对基材弹性的描述。尽管第二个模型在弹性方面更具经验性,但它可以实现软润湿动力学的梯度动力学公式。我们提供了两个模型预测的平衡状态之间的详细比较,在这种模型的存在下,我们从中推断出柔软润湿的强大特征。具体而言,我们表明,“干”和“湿”状态之间的(a)对称性对底物的水平变形。根据最新的实验,讨论了我们的结果。
The wetting of soft polymer substrates brings in multiple complexities as compared to the wetting on rigid substrates. The contact angle of the liquid is no longer governed by Young's law, but is affected by the substrate's bulk and surface deformations. On top of that, elastic interfaces exhibit a surface energy that depends on how much they are stretched -- a feature known as the Shuttleworth effect (or as surface-elasticity). Here we present two models by which we explore the wetting of drops in the presence of a strong Shuttleworth effect. The first model is macroscopic in character and consistently accounts for large deformations via a neo-Hookean elasticity. The second model is based on a mesoscopic description of wetting, using a reduced description of the substrate's elasticity. While the second model is more empirical in terms of the elasticity, it enables a gradient dynamics formulation for soft wetting dynamics. We provide a detailed comparison between the equilibrium states predicted by the two models, from which we deduce robust features of soft wetting in the presence of a strong Shuttleworth effect. Specifically, we show that the (a)symmetry of the Shuttleworth effect between the "dry" and "wet" states governs horizontal deformations in the substrate. Our results are discussed in the light of recent experiments on the wettability of stretched substrates.