论文标题

在波动电势中扩散的非平衡热力学

Non-equilibrium thermodynamics of diffusion in fluctuating potentials

论文作者

Alston, Henry, Cocconi, Luca, Bertrand, Thibault

论文摘要

稳定状态下的熵产生速率是真正非平衡过程的独特特征。精确的结果虽然通常仅限于简单的模型,但却提供了一个独特的机会,可以详细介绍这些过程的热力学特征。在这里,我们得出了通过任意形状的外部潜力的波动驱动的单个粒子系统中熵产生的稳态结果的分析结果。随后,我们为谐波陷阱中的扩散粒子提供了确切的结果,该谐波陷阱的潜在刚度根据离散和连续的马尔可夫过程在时间上变化。特别是,研究具有完全间歇性潜力的情况使我们能够引入有效的随机重置模型,以便为此获得有限的非负熵产生。总的来说,这项工作为波动电势的非平衡热力学理论奠定了基础,并立即应用于随机重置过程,光学陷阱中的波动以及生活系统中的波动相互作用。

A positive rate of entropy production at steady state is a distinctive feature of truly non-equilibrium processes. Exact results, while being often limited to simple models, offer a unique opportunity to explore the thermodynamic features of these processes in full details. Here we derive analytical results for the steady-state rate of entropy production in single particle systems driven away from equilibrium by the fluctuations of an external potential of arbitrary shapes. Subsequently, we provide exact results for a diffusive particle in a harmonic trap whose potential stiffness varies in time according to both discrete and continuous Markov processes. In particular, studying the case of a fully intermittent potential allows us to introduce an effective model of stochastic resetting for which it is possible to obtain finite non-negative entropy production. Altogether, this work lays the foundation for a non-equilibrium thermodynamic theory of fluctuating potentials, with immediate applications to stochastic resetting processes, fluctuations in optical traps and fluctuating interactions in living systems.

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