论文标题
地球积聚期间碳的金属硅酸盐分配及其在早期太阳系中的分布
The Metal-Silicate Partitioning of Carbon During Earth's Accretion and its Distribution in the Early Solar System
论文作者
论文摘要
碳是地球生命的存在和演变的基本要素。鉴于在低压和温度下碳是强烈的铁质刺激(爱金属),因此它在地球的地壳和地幔中的丰富度非常高,因此在积聚期间几乎应该完全隔离到地球的核心中。 BSE中碳浓度的估计值在100-260 ppm的范围内,并且基于简单的核心壳分化模型,比预期的要高得多。在这里,我们通过在地球核心形成(49-71 GPA和3600-4000 K)的假定条件下进行的实验表明,在这些条件下的碳比在低压下($ \ \\ leq $ 13 GPA)和温度($ \ \ \ \ \ \\ leq $ 2500 k)在这些条件下要比以前的大型新闻相似,但要比以前的大型新闻相比,在这些条件下,碳质量明显少得多。我们的。使用我们的新数据以及先前发布的结果,我们得出了碳金属硅酸盐分配的压力温度依赖性的新参数化。我们将此参数化应用于结合基于天体物理N体积聚模拟的行星形成和核心掩体分化的模型。由于由于高温下的升华,分化的行星几乎在碳中几乎完全耗尽,因此BSE中几乎所有碳都是通过外部太阳能系统的完全氧化碳质软管材料的积聚而添加的。在整个积聚过程中,将碳连续添加到地幔中,其浓度在增生结束时达到BSE范围内的值(例如140 $ \ pm $ 40 ppm)。相应的最终核心和散装地球碳浓度分别为1270美元$ \ $ 300 ppm和495 $ \ pm $ 125 ppm。
Carbon is an essential element for the existence and evolution of life on Earth. Its abundance in Earth's crust and mantle (the Bulk Silicate Earth, BSE) is surprisingly high given that carbon is strongly siderophile (metal-loving) at low pressures and temperatures, and hence should have segregated almost completely into Earth's core during accretion. Estimates of the concentration of carbon in the BSE lie in the range 100-260 ppm and are much higher than expected based on simple models of core-mantle differentiation. Here we show through experiments at the putative conditions of Earth's core formation (49-71 GPa and 3600-4000 K) that carbon is significantly less siderophile at these conditions than at the low pressures ($\leq$13 GPa) and temperatures ($\leq$2500 K) of previous large volume press studies, but at least an order of magnitude more siderophile than proposed recently based on an experimental approach that is similar to ours. Using our new data along with previously published results, we derive a new parameterization of the pressure-temperature dependence of the metal-silicate partitioning of carbon. We apply this parameterization in a model that combines planet formation and core-mantle differentiation that is based on astrophysical N-body accretion simulations. Because differentiated planetesimals were almost completely depleted in carbon due to sublimation at high temperatures, almost all carbon in the BSE was added by the accretion of fully-oxidized carbonaceous chondrite material from the outer solar system. Carbon is added to the mantle continuously throughout accretion and its concentration reaches values within the BSE range (e.g. 140$\pm$40 ppm) at the end of accretion. The corresponding final core and bulk Earth carbon concentrations are 1270$\pm$300 ppm and 495$\pm$125 ppm respectively.