论文标题
由rb $ _2 $ _2 $ _3 $ _3 $ se $ _4 $带有kagome lattice的压力引起的LIFSHITZ过渡引起的超导率
Superconductivity arising from pressure induced Lifshitz transition in Rb$_2$Pd$_3$Se$_4$ with kagome lattice
论文作者
论文摘要
根据Bardeen-Cooper-Schrieffer(BCS)理论,超导性通常需要具有较强的电子偶耦合和中等状态的中等准粒子密度(DOS)的费米表面(S)。 kagome晶格可以容纳平坦的乐队和拓扑狄拉克带。同时,由于平行的费米表面和鞍点,预计会有许多有趣的命令。在这里,我们通过使用DAC Anvil加压kagome复合RB $ _2 $ _3 $ _3 $ _3 $ _4 $来报告对超导性的观察。母体化合物显示出绝缘的行为;但是,当施加高压时,它逐渐变成金属,并转向超导状态。高压同步子测量结果表明,在此过渡过程中没有发生结构过渡。密度功能理论(DFT)计算表明,父阶段的绝缘行为是由于部分PD-4D $ T_ {2G} $ bands和Se-derivivative 4 $ p $ -band的结晶场分裂引起的。但是,当Lifshitz过渡发生时,达到了金属性和超导性的阈值,导致小费米表面出现在$γ$点处。我们的结果指出了非常规的超导性,并为了解Kagome材料的电子演化提供了新的启示。
According to the Bardeen-Cooper-Schrieffer (BCS) theory, superconductivity usually needs well defined Fermi surface(s) with strong electron-phonon coupling and moderate quasiparticle density of states (DOS). A kagome lattice can host flat bands and topological Dirac bands; meanwhile, due to the parallel Fermi surfaces and the saddle points, many interesting orders are expected. Here, we report the observation of superconductivity by pressurizing a kagome compound Rb$_2$Pd$_3$Se$_4$ using a DAC anvil. The parent compound shows an insulating behavior; however, it gradually becomes metallic and turns to a superconducting state when a high pressure is applied. High pressure synchrotron measurements show that there is no structural transition occurring during this transition. The density-functional-theory (DFT) calculations illustrate that the insulating behavior of the parent phase is due to the crystalline field splitting of the partial Pd-4d $t_{2g}$ bands and the Se-derivative 4$p$-band. However, the threshold of metallicity and superconductivity are reached when the Lifshitz transition occurs, leading to the emergence of tiny Fermi surface at $Γ$ point. Our results point to an unconventional superconductivity and shed new light on understanding the electronic evolution of a kagome material.