论文标题
转移的大气压力等离子射流的不同配置及其在聚合物处理中的应用
Different configurations of transferred atmospheric pressure plasma jet and their application to polymer treatment
论文作者
论文摘要
在大量应用中使用大气压力等离子体喷气机(APPJ)受到与处理区域的大小和到达目标的困难有关的逆境。在其结构中使用长管的设备的使用为克服这些挑战做出了重大贡献。在这项工作中,提出了两种采用喷气转移技术的不同等离子体系统之间的比较。两个设备之间的主要区别是如何组装长塑料管。第一个使用铜线放置在长塑料管中。另一个设备的金属网格安装在两个同轴塑料管之间的同心布置中。结果,两个APPJ系统具有不同的特性,与网格安装相比,电流组件的功能更强大,也具有更高的电流和旋转温度值。 X射线光电子光谱(XPS)表明,这两种构型都能够在聚丙烯(PP)表面插入含O的官能团。但是,带有电线组件的传输等离子射流能够在PP表面添加更多官能团。 XPS分析的结果通过水接触角度测量(WCA)佐证,因为当PP表面呈现较高量的O含O的基团时,获得了较低的WCA值。表面形态的评估表明,血浆处理倾向于使用电线和网状构型略微增加PP样品的表面粗糙度。此外,这项工作中的发现表明,具有电线配置的APPJ更适合物质处理,而带有网格布置的转移喷气机倾向于呈现较低的电流值,这使其更适合生物应用。
The employment of atmospheric pressure plasma jets (APPJs) in a large sort of applications is limited by the adversities related to the size of the treated area and the difficulty to reach the target. The use of devices that employ long tubes in their structure has contributed significantly to overcome these challenges. In this work, a comparison between two different plasma systems employing the jet transfer technique is presented. The main difference between the two devices is how the long plastic tube was assembled. The first one uses a copper wire placed inside a long plastic tube. The other device has a metallic mesh installed in a concentric arrangement between two coaxial plastic tubes. As a result, the two APPJ systems exhibit different properties, with the wire assembly being more powerful, also presenting higher values for the electrical current and rotational temperature when compared to the mesh mounting. X-ray photoelectron spectroscopy (XPS) demonstrates that both configurations were capable of inserting O-containing functional groups on the polypropylene (PP) surface. However, the transferred plasma jet with wire assembly was able to add more functional groups on the PP surface. The results from XPS analysis were corroborated with water contact angle measurements (WCA), being that lower WCA values were obtained when the PP surface presented higher amounts of O-containing groups. Surface morphology evaluation showed that the plasma treatment tends to slightly increase the surface roughness of the PP samples with both wire and mesh configurations. Furthermore, the findings in this work suggest that the APPJ with wire configuration is more appropriate for material treatments, while the transferred jet with mesh arrangement tends to present lower electrical current values which makes it more suitable for biological applications.