论文标题
无PB(1-X)BA(ZR0.2TI0.8)O3-X(BA0.7CA0.3)TIO3 Ceramics中局部结构异质性和远距离铁电性的共存
Coexistence of local structural heterogeneities and long-range ferroelectricity in Pb-free (1-x)Ba(Zr0.2Ti0.8)O3-x(Ba0.7Ca0.3)TiO3 ceramics
论文作者
论文摘要
环境良性(1-x)ba(ti $ _ {0.8} $ zr $ _ {0.2} $)o $ $ _3 $ -x(ba $ _ {0.7} $ ca $ _ {0.3} $ _ {0.3} $)莱特牧师。 \ textbf {103},257602(2009)]。在这封信中,通过关注局部和平均结构与宏观机电和介电测量相结合,我们证明了四方BZT-BCT陶瓷中的结构性质关系。在高温立方至四方相变的过程中,在低于$ \ sim $ 477 k的温度下,通过自发体积的铁电驱动器来表现出极性纳米区域。八面体。这些八面体在两极分化过程中损害了他们的个性。通过压电响应力显微镜观察到嵌入在T $ _ {M} $以下的宏观铁电区域内的域域的存在以及它们的分层排列。当比较polded和未固定样品的极性化时,也观察到结构/极性异质性的存在的效果。发现固定样品更容易受到电场的影响。此外,通过使用依赖电场的X射线衍射研究,我们还表明,该磁场下的陶瓷显示了四方变形的减少,这与较早的报告一致。
Environmentally benign (1-x)Ba(Ti$_{0.8}$Zr$_{0.2}$)O$_3$-x(Ba$_{0.7}$Ca$_{0.3}$)TiO$_3$ (BZT-BCT) ceramics are promising materials due to their remarkable high piezoresponse [Liu and Ren, Phys. Rev. Lett. \textbf{103}, 257602 (2009)]. In this Letter, by focusing on local and average structure in combination with macroscopic electromechanical and dielectric measurements we demonstrate the structure property relationship in the tetragonal BZT-BCT ceramic. During high-temperature cubic to tetragonal phase transformation, polar nanoregions are manifested through the spontaneous volume ferroelectrostriction at temperatures below $\sim$ 477 K. Temperature-dependent local structural investigations across the Zr K edge extended x-ray absorption fine structure spectroscopy reveal an anomalous collaboration between the ZrO$_{6}$ and TiO$_6$ octahedra. These octahedra compromise their individuality during polarization development. The presence of domains of submicron size embedded inside the macroscopic ferroelectric regions below T$_{m}$, as well as their hierarchical arrangement, is observed by piezo-response force microscopy. Effects of the existence of the structural/polar heterogeneities below T$_{m}$ are observed also when polarizibilities of the poled and the unpoled samples are compared; the poled sample is found to be more susceptible to the electric field. In addition, by using electric field dependent x-ray diffraction studies we also show that this ceramic under field exhibits reduction of tetragonal distortion, which is consistent with earlier reports.