论文标题
在磁性稀土上调节低温Jahn-Teller转变温度
Tuning cryogenic Jahn-Teller transition temperatures in magnetoelectric rare earth vanadates
论文作者
论文摘要
Few materials undergo cooperative Jahn-Teller (JT) transitions at low temperatures, but zircon-type oxides are one class that includes DyVO$_4$, which transforms from a tetragonal to an orthorhombic structure at around 13.6 K, with a narrow transition temperature range within 0.5 K. Since many rare-earth ions can be accommodated in the structure, there should be ample routes to vary the transition temperature and过渡的结构效应。我们已经合成了纯dyvo $ _4 $和实心解决方案dy $ _ {1-x} $ tm $ _x $ _x $ vo $ _4 $($ x $ x $ = 0.05、0.1、0.1、0.15、0.2和0.5)和dy $ _ {1-y}降水。 X射线衍射显示了系统的峰值移动和晶格参数的线性变化,随着替代的增加。我们通过热容量测量表明,TM $^{3+} $和pr $^{3+} $替换会导致合作JT过渡温度的抑郁。当替代水平增加时,JT过渡最终被抑制。我们检查了一个平均场近似模型,该模型可以解释JT过渡温度变化及其最终消失。已知这些锆石型氧化物中的合作JT效应表现出较大的磁反应,应从平均场行为遵循。可以通过衍射轻松检测结构转化,并可以用作低温实验中的温度校准。
Few materials undergo cooperative Jahn-Teller (JT) transitions at low temperatures, but zircon-type oxides are one class that includes DyVO$_4$, which transforms from a tetragonal to an orthorhombic structure at around 13.6 K, with a narrow transition temperature range within 0.5 K. Since many rare-earth ions can be accommodated in the structure, there should be ample routes to vary the transition temperature and structural effects of the transition. We have synthesized pure DyVO$_4$ and solid solutions Dy$_{1-x}$Tm$_x$VO$_4$ ($x$ = 0.05, 0.1, 0.15, 0.2, and 0.5) and Dy$_{1-y}$Pr$_y$VO$_4$ ($y$ = 0.03, 0.05, 0.1, 0.2, and 0.5), all by solution precipitation. X-ray diffraction shows a systematic peak shift and a linear change of lattice parameters with increasing substitution. We demonstrate through heat capacity measurements that both Tm$^{3+}$ and Pr$^{3+}$ substitutions cause a depression of the cooperative JT transition temperature. When the substitution level increases, the JT transition is eventually suppressed. We examine a mean-field approximation model that can explain the both the JT transition temperature shift and its eventual disappearance. The cooperative JT effect in these zircon-type oxides is known to exhibit a large magnetoelectric response, which should follow from the mean-field behavior. The structural transformation can be easily detected via diffraction and can be used as a temperature calibration in low temperature experiments.