论文标题

剥离淬灭碳质复合材料(D-QCC)拉伸带强度的实验室测量

Laboratory measurements of stretching band strengths of deuterated Quenched Carbonaceous Composites (D-QCC)

论文作者

Mori, Tamami, Onaka, Takashi, Sakon, Itsuki, Buragohain, Mridusmita, Takahata, Naoto, Sano, Yuji, Pathak, Amit

论文摘要

观察到的星际培养基(ISM)中氘(D)的丰度差异很大,这表明大量的D可能会耗尽到多环芳烃(PAHS)中。预计PAH的养育的签名将通过4.4--4.7微米的C伸展模式最清楚地出现,其发射光谱的强度相对于C-H伸展模式的强度为3.3---3.5微米的C-H伸展模式的优势,一旦我们在两种拉伸模式的相对带强度的相对带强度上都提供了PAH的氢(H)的相对丰度。我们报告了相对于C-H的C-D拉伸模式的带强度的实验结果。我们通过用CH $ _4 $和CD $ _4 $具有各种比例的混合物代替CH $ _4 QCC的起始气体,以使用各种比例来代替CH $ _4 $ _4 QCC的起始气体,采用了星际碳尘,淬火的碳质粉(QCC)和合成的技术质量QCC(D-QCC)的实验室类似物。采用D-QCC的红外光谱来估计拉伸模式的相对带强度,而D-QCC样品中的D/H比则使用纳米级次级离子质谱仪(Nanosims)测量。我们得到芳香族和脂肪族C-D对C-H伸展的相对强度分别为0.56 +/- 0.04和0.38 +/- 0.01/d/h。芳族拉伸的比率与理论计算的结果非常吻合,而脂肪族伸展的结果比芳香族小。目前的结果不会显着改变先前从观察到的光谱估算的星际PAH的D/H比。

The observed large variation in the abundance of deuterium (D) in the interstellar medium (ISM) suggests that a significant fraction of D may be depleted into polycyclic aromatic hydrocarbons (PAHs). Signatures of deuteration of PAHs are expected to appear most clearly through C-D stretching modes at 4.4--4.7 micron, whose strengths in emission spectra relative to those of C-H stretching modes at 3.3--3.5 micron provide the relative abundance of D to hydrogen (H) in PAHs once we have accurate relative band strengths of both stretching modes. We report experimental results of the band strength of C-D stretching modes relative to C-H. We employ a laboratory analogue of interstellar carbonaceous dust, Quenched Carbonaceous Composite (QCC), and synthesize deuterated QCC (D-QCC) by replacing the starting gas of CH$_4$ of QCC by mixtures of CH$_4$ and CD$_4$ with various ratios. Infrared spectra of D-QCC are taken to estimate the relative band strengths of the stretching modes, while the D/H ratios in the D-QCC samples are measured with a nano-scale secondary ion mass spectrometer (NanoSIMS). We obtain that the relative strength of aromatic and aliphatic C-D to C-H stretches is 0.56 +/- 0.04 and 0.38 +/- 0.01 per D/H, respectively. The ratio for the aromatic stretches is in good agreement with the results of theoretical calculations, while that of aliphatic stretches is smaller than that of aromatic. The present results do not significantly change the D/H ratios in the interstellar PAHs previously estimated from observed spectra.

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