论文标题
激子旋转混合的精确波长跟踪
Accurate wavelength tracking by exciton spin mixing
论文作者
论文摘要
波长区分系统通常由重型台式仪器组成,包括衍射光学器件,运动部件和相邻检测器。对于简单的波长测量值,例如实验室光源校准或激光波长跟踪,这些跟踪不需要多色分析,无法处理笨重的光谱仪器,轻巧,易于过程和灵活的单像素设备引起了越来越多的关注。在这里,我们提出了一种用于波长跟踪的设备,其功能核心的室温磷光是在其功能的核心上,该设备显示出一个纳米及以下的分辨率。它是从一个包含有机室温磷光器和胶体量子点的单个宿主 - 圈系统中处理的解决方案。光致发光层中激发的三胞胎状态的份额取决于激发波长,并决定了膜的余滴强度,该膜由简单的光电探测器跟踪。最后,在我们的新型测量概念成功取代了全光谱仪的情况下,证明了全有机薄膜波长传感器和两个应用。
Wavelength discriminating systems typically consist of heavy benchtop-based instruments, comprising diffractive optics, moving parts, and adjacent detectors. For simple wavelengths measurements, such as lab-on-chip light source calibration or laser wavelength tracking, which do not require polychromatic analysis and cannot handle bulky spectroscopy instruments, light-weight, easy-to-process, and flexible single-pixel devices are attracting increasing attention. Here, we propose a device for wavelength tracking with room-temperature phosphorescence at the heart of its functionality that demonstrates a resolution down to one nanometer and below. It is solution-processed from a single host-guest system comprising organic room-temperature phosphors and colloidal quantum dots. The share of excited triplet states within the photoluminescent layer is dependent on the excitation wavelength and determines the afterglow intensity of the film, which is tracked by a simple photodetector. Finally, an all-organic thin-film wavelength sensor and two applications are demonstrated where our novel measurement concept successfully replaces a full spectrometer.