论文标题

核壳铁电纳米颗粒中迷宫域结构的电场控制

Electric field control of labyrinth domain structures in core-shell ferroelectric nanoparticles

论文作者

Morozovska, Anna N., Eliseev, Eugene A., Cherifi-Hertel, Salia, Evans, Dean R., Hertel, Riccardo

论文摘要

在Landau-Ginzburg-Devonshire(LGD)方法的框架中,我们研究了通过纳米化的铁电芯中的同质外部电场控制平衡结构域结构的极性和手性的可能性。在某些筛选长度和核心大小下,由Landau-Devonshire Energy,Ginzburg极化梯度能和静电项组成的LGD能量的最小值导致核心中稳定的迷宫域结构的自发外观。迷宫是从由任意小的随机定向纳米域组成的初始极化分布演变而来的。平衡迷宫结构受到初始极化分布的细节的影响很小,因此可以获得几乎退化迷宫结构的准核,其数量仅受网格离散密度的限制。将同质电场应用于带迷宫域的纳米颗粒,然后将其删除,允许诱导迷路结构的变化,因为迷宫极性受到粒子极性轴上的磁场投影的控制。在筛选电荷松弛的特定条件下,迷宫结构的准静态介电敏感性可能为负,可能导致负电容效应。考虑到LGD方法的一般有效性,我们期望在许多空间限制的纳米化铁龙中可以对迷路结构域进行电场控制,这对于先进的加密和现代纳米电子学可能会很有趣。

In the framework of the Landau-Ginzburg-Devonshire (LGD) approach, we studied the possibility of controlling the polarity and chirality of equilibrium domain structures by a homogeneous external electric field in a nanosized ferroelectric core covered with an ultra-thin shell of screening charge. Under certain screening lengths and core sizes, the minimum of the LGD energy, which consists of Landau-Devonshire energy, Ginzburg polarization gradient energy, and electrostatic terms, leads to the spontaneous appearance of stable labyrinth domain structures in the core. The labyrinths evolve from an initial polarization distribution consisting of arbitrarily small randomly oriented nanodomains. The equilibrium labyrinth structure is weakly influenced by details of the initial polarization distribution, such that one can obtain a quasi-continuum of nearly degenerate labyrinth structures, whose number is limited only by the mesh discretization density. Applying a homogeneous electric field to a nanoparticle with labyrinth domains, and subsequently removing it, allows inducing changes to the labyrinth structure, as the maze polarity is controlled by a field projection on the particle polar axis. Under specific conditions of the screening charge relaxation, the quasi-static dielectric susceptibility of the labyrinth structure can be negative, potentially leading to a negative capacitance effect. Considering the general validity of the LGD approach, we expect that an electric field control of labyrinth domains is possible in many spatially-confined nanosized ferroics, which can be potentially interesting for advanced cryptography and modern nanoelectronics.

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