论文标题

各向异性旋转玻璃Fe $ _2 $ tio $ _5 $中的波动和静态自旋相关的中子散射研究

Neutron Scattering Study of Fluctuating and Static Spin Correlations in the Anisotropic Spin Glass Fe$_2$TiO$_5$

论文作者

Li, Yu, LaBarre, P. G., Pajerowski, D. M., Ramirez, A. P., Rosenkranz, S., Phelan, D.

论文摘要

各向异性旋转玻璃过渡,其中仅在pseudobrookite fe $ _2 $ tio $ _5 $中沿C轴观察到自旋冰冻,因为预计Fe $^{3+} $ amments(D $^5 $)预计将是同位素的。最近,中子衍射表明,冲浪板形的抗磁性纳米磁铁在玻璃过渡温度以上的融合,t $ _g $ $ \约$ 55 k,并提出了一种模型,其中型号冻结了冲浪板的磁化磁化强度导致Anisotropic旋转玻璃玻璃玻璃玻璃状态。鉴于这个新模型,我们已经对自旋旋转相关性进行了高分辨率的非弹性中子散射测量测量,以了解surfboard旋转动力学对中子(picsecond)时间尺度的温度依赖性。在这里,我们报告了从单晶Fe $ _2 $ tio $ _5 $测量的自旋波动的温度依赖性。强烈的准弹性磁散射是由surfboard相关性引起的,远高于t $ _g $。自旋波动具有陡峭的能波矢量关系,并表明与较大的居里 - 韦斯温度一致的强烈交换相互作用。随着温度从上面的t $ _g $接近t $ _g $,观察到光谱重量从非弹性转向弹性散射。在4 K和300 K之间的各种温度下,确定波动的特征放松率。 Despite the freezing of the majority of the spin correlations, an inelastic contribution remains even at base temperature, signifying the presence of fluctuating intra-surfboard spin correlations to at least T/T$_g$ $\approx$ 0.1 consistent with a description of Fe$_2$TiO$_5$ as a hybrid between conventional and geometrically frustrated spin glasses.

The anisotropic spin glass transition, in which spin freezing is observed only along the c-axis in pseudobrookite Fe$_2$TiO$_5$, has long been perplexing because the Fe$^{3+}$ moments (d$^5$) are expected to be isotropic. Recently, neutron diffraction demonstrated that surfboard-shaped antiferromagnetic nanoregions coalesce above the glass transition temperature, T$_g$ $\approx$ 55 K, and a model was proposed in which the freezing of the fluctuations of the surfboards' magnetization leads to the anisotropic spin glass state. Given this new model, we have carried out high resolution inelastic neutron scattering measurements of the spin-spin correlations to understand the temperature dependence of the intra-surfboard spin dynamics on neutron (picosecond) time-scales. Here, we report on the temperature-dependence of the spin fluctuations measured from single crystal Fe$_2$TiO$_5$. Strong quasi-elastic magnetic scattering, arising from intra-surfboard correlations, is observed well above T$_g$. The spin fluctuations possess a steep energy-wave vector relation and are indicative of strong exchange interactions, consistent with the large Curie-Weiss temperature. As the temperature approaches T$_g$ from above, a shift in spectral weight from inelastic to elastic scattering is observed. At various temperatures between 4 K and 300 K, a characteristic relaxation rate of the fluctuations is determined. Despite the freezing of the majority of the spin correlations, an inelastic contribution remains even at base temperature, signifying the presence of fluctuating intra-surfboard spin correlations to at least T/T$_g$ $\approx$ 0.1 consistent with a description of Fe$_2$TiO$_5$ as a hybrid between conventional and geometrically frustrated spin glasses.

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