论文标题
梗的平衡溶液部分被另一种液体覆盖
Equilibrium solutions of a sessile drop partially covered by another liquid
论文作者
论文摘要
当我们研究水平底物的顶部均方根滴的平衡溶液被另一种不可识别的液体部分覆盖时,因此该液滴与第三液(通常为空气)接触。界面的形状是通过在三个流体连接处的诺伊曼和扬定律(三点)和两种流体(底物)以及轴向对称性容器壁上的no-flow flow边界条件的两种流体接触线(三重点)和两种流体(在底物上)以及两种流体接触线(在底物)以及两种流体的接触线(三重点)和两种流体(在底部的底物)中获得的微分方程的数值集成。该公式表明该溶液是通过四个无量纲变量参数化的,该变量代表:i)容器中外部液体的体积,ii)界面张力的两个比例,iii)底物处液体滴的接触角。在此参数空间中,我们找到由三个接口组成的解决方案:一个将基板与三个点连接起来,两个将此点与对称轴和壁连接起来的解决方案。我们发现,第一个界面的形状很大程度上取决于外部液体的高度,而触点和表面张力的两个比率并未引入定性变化。特别是,根据外部流体的有效高度的值,该溶液可以显示一个或多个颈部,甚至根本没有颈部。充满活力的分析可以预测颈部的破裂,这可能会给由无柄滴和浮动镜头形成的分离系统提供位置,以及两者之间的最终球形液滴(取决于分裂的数量)。
We study the equilibrium solutions of a sessile drop on top of a horizontal substrate when it is partially covered by another inmiscible liquid, so that part of the drop is in contact with a third fluid (typically, air). The shapes of the interfaces are obtained by numerical integration of the differential equations resulting from the application of the Neumann's and Young's laws at the three fluids junction (triple point) and the two fluids--solid contact line (at the substrate), as well as no--flow boundary conditions at the wall of the container under axial symmetry. The formulation shows that the solutions are parametrized by four dimensionless variables, which stand for: i) the volume of the external liquid in the container, ii) two ratios of interfacial tensions, and iii) the contact angle of the liquid drop at the substrate. In this parameters space, we find solutions that consist of three interfaces: one which connects the substrate with the triple point, and two that connect this point with the symmetry axis and the wall. We find that the shape of the first interface strongly depend on the height of the external liquid, while the contact angle and the two ratios of surface tensions do not introduce qualitative changes. In particular, the solution can show one or more necks, or even no neck at all, depending on the value of the effective height of the external fluid. An energetic analysis allows to predict the breakups of the necks, which could give place to separated systems formed by a sessile drop and a floating lens, plus eventual spherical droplets in between (depending on the number of breakups).