论文标题
阻燃剂对部分预混合层状火焰的侧壁淬火的影响
Effect of flame retardants on side-wall quenching of partially premixed laminar flames
论文作者
论文摘要
进行了侧壁淬灭(SWQ)的部分预混合层状甲烷 - 空气火焰(SWQ)的结合实验和数值研究。建立了一个完善的SWQ燃烧器,以允许从(次级)墙壁入口靠近火焰淬火点发出的其他气态产品播种。首先,使用平面激光诱导的OH自由基荧光测量结果评估了部分预混合的火焰的特性,并进行了完全分辨的运输和化学的相应数值模拟。在壁上形成了富集混合物的边界层,导致与壁的反应区,以从壁入口的高注入速率。随后,在一项数值研究中,壁流入与基于磷光器的阻燃剂的二甲基甲基磷酸(DMMP)混合。 DMMP添加允许评估热量损失和阻燃剂对火焰壁相互作用期间火焰结构的综合作用。随着注入的混合物的DMMP量增加,火焰稳定在远离墙壁的情况下,显示局部热释放速率的降低。因此,最大壁热通量大大减少。这导致淬火壁上的热负荷较低。火焰结构分析表明,中间物种在壁上的积累,类似于在没有阻止火焰的预混合火焰淬灭时CO积累的积累。该研究表明,部分预混合火焰的结构如何受到释放额外燃料或燃料和阻燃剂混合物的壁的影响。从规范配置中获得的见解可以更好地理解近壁火焰中火焰阻燃剂和热量损失的综合作用。
A combined experimental and numerical investigation of partially premixed laminar methane-air flames undergoing side-wall quenching (SWQ) is performed. A well-established SWQ burner is adapted to allow the seeding of the main flow with additional gaseous products issued from a (secondary) wall inlet close to the flame's quenching point. First, the characteristics of the partially premixed flame that quenches at the wall are assessed using planar laser-induced fluorescence measurements of the OH radical, and a corresponding numerical simulation with fully-resolved transport and chemistry is conducted. A boundary layer of enriched mixture is formed at the wall, leading to a reaction zone parallel to the wall for high injection rates from the wall inlet. Subsequently, in a numerical study, the wall inflow is mixed with dimethylmethylphosphonat (DMMP), a phosphor-based flame retardant. The DMMP addition allows the assessment of the combined effects of heat loss and flame retardants on the flame structure during flame-wall interaction. With an increasing amount of DMMP in the injected mixture, the flame stabilizes further away from the wall and shows a decrease in the local heat-release rate. Thereby, the maximum wall heat flux is significantly reduced. That results in a lower thermal load on the quenching wall. The flame structure analysis shows an accumulation of the intermediate species HOPO at the wall similar to the CO accumulation during the quenching of premixed flames without flame retardant addition. The study shows how the structure of a partially premixed flame is influenced by a wall that releases either additional fuel or a mixture of fuel and flame retardant. The insights gained from the canonical configuration can lead to a better understanding of the combined effects of flame retardants and heat losses in near-wall flames.